Explosion and Fire at Formosa Plastics Corporation, USA, Illiopolis, Illinois PVC comes in two basic forms: rigid (sometimes abbreviated as RPVC) and flexible. Chemical hazards in drinking-water: Vinyl chloride. Vinyl Chloride is highly reactive and can react with oxidizing agents and many other organic compounds. Exposure to vinyl chloride occurs mainly in the workplace. Vinyl Chloride Monomer Chloroethylene 200-831-0 75-01-4 > 99.9% F+; R12 Carc. Reproductive Hazard Vinyl Chloride may damage the developing fetus. Beilstein/REAXYS Number 1731576 . Vinyl chloride has been used in the past as a refrigerant. contact with liquid may cause frostbite to exposed tissue. IF exposed or concerned: Get medical attention. Canadian Ingredient Disclosure List . Vinyl chloride liquid and vapour are highly flammable. causes damage to liver, … Leaking gas fire: Do not extinguish, unless leak can be stopped safely. First, men occupationally exposed to vinyl chloride have experienced a specific hazard of angiosarcoma of the liver. 2.2 Vinyl Chloride Monomer (VCM) Process 7 2.2.1 Oxychlorination Process 9 2.3 Dynamics Simulation 12 ... hazard, safety and pollution. SAFETY DATA SHEET VINYL CHLORIDE MONOMER Issue Date: 12/06/2007 Reviewed Date: 01/08/2016 Page 2 of 17 … causes skin irritation. At high concentrations, it has a sweet odor typical of chlorinated hydrocarbons. Eliminate all ignition sources if safe to do so. It is also known as chloroethene, chloroethylene, ethylene monochloride, or monochloroethylene. The presence of oxygen stimulates the degradation of vinyl chloride and is the basis upon which ORC has been shown to effectively treat this contaminant. This colorless compound is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC). At concentrations of about 3.6 percent VCM in air, VCM can be an explosion hazard. Molecular Weight 62.50 . Hazards identification Response :Get medical attention if you feel unwell. It is not intended to be a comprehensive treatise on the chemical or toxicological nature of vinyl chloride. Vinyl Chloride can be an explosion hazard at concentrations from approximately 3.6 percent to 33 percent Vinyl Chloride in air. VCM is often stored as a liquid under pressure. Vinyl Chloride Section 2. Gas LG; H280 Carc. Most vinyl chloride is used to make polyvinyl chloride (PVC) plastic and vinyl products. Category 1. Polyvinyl chloride (PVC or vinyl) is the most toxic plastic for our health and the environment. Protect from sunlight. (iii) Employers shall include vinyl chloride in the hazard communication program established to comply with the HCS (1910.1200). DRAFT DRAFT FOR PUBLIC COMMENT AND ii SCIENTIFIC REVIEW October 1999 LIST OF CONTRIBUTORS. Vinyl chloride is a colorless gas at normal temperatures. Eye damage/eye irritation. Vinyl chloride is considered in the WHO Guidelines for Drinking-water Quality (GDWQ). About 13 billion kilograms are produced annually. Category 2. Employers shall include vinyl chloride in the hazard communication program established to comply with the HCS (§1910.1200). It has been shown to cause liver, brain, lung, and other types of cancer. Storage :Store locked up. Vinyl chloride is an organochloride with the formula H2C=CHCl that is also called vinyl chloride monomer (VCM) or chloroethene. Aerobic … may cause respiratory irritation. Vinyl chloride ≥99.5% Synonym: Chloroethylene CAS Number 75-01-4. Gas 1; H220 Press. may cause cancer. Vinyl chloride: incident management Ref: PHE publications gateway number 2014790 PDF , 77.3KB , 11 pages This file may not be suitable for users of assistive technology. Polyvinyl Chloride 39002-86-2 99+% 15 mg/m as Nuisance Dust 15 mg/m3 as Nuisance Dust Bis(2 -ethylhexyl) Phthalate* 117-81-7 < 1% 5 mg/m3 5 mg/m3 Vinyl Chloride Monomer** 75-01-4 < 8.5 ppm 1 ppm 5 ppm * Bis( 2-ethylhexyl) phthalate is an NTP anticipated human carcinogen and IARC possible human carcinogen. concentrations” (PNEC), expressed as a hazard quotient for the marine aquatic environment. Vinyl chloride is used to make polyvinyl chloride (PVC). Linear Formula H 2 C=CHCl . Acute (short-term) exposure to high levels of vinyl chloride in air has resulted in central nervous system (CNS) effects, such as dizziness, drowsiness, and headaches in humans. Vinyl Chloride is practically insoluble in water. The required development the software of chemical process gives significant impact in chemical process simulation. History. Store in a well-ventilated place. Breathing vinyl chloride for long periods of time can result in permanent liver damage, immune reactions, nerve damage, and liver cancer. causes eye irritation. The liquid evaporates readily at ambient temperatures. Employers shall ensure that each employee has access to labels on containers of vinyl chloride and to safety data sheets, and is trained in accordance with the requirements of HCS and paragraph (j) of this section. PVC was discovered accidentally in the early 19 th century when the polymer appeared as a white solid inside sunlight-exposed flasks of vinyl chloride. Global Harmonization System (GHS) Classification: Category 2 . To determine the PNEC value, three different trophic levels are considered: aquatic plants, invertebrates and fishes. MDL number MFCD00040415. Vinyl chloride is an organochloride with the formula H2C=CHCl that is also called vinyl chloride monomer (VCM) or chloroethene. Section 16 - Additional Information … Polyvinyl chloride (colloquial: polyvinyl, vinyl; abbreviated: PVC) is the world's third-most widely produced synthetic plastic polymer (after polyethylene and polypropylene).About 40 million tons of PVC are produced each year. Second, any other occupational hazards that may have existed have been small. 1; R45 Flam. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. On both occasions, the polymer appeared as a white solid inside flasks of vinyl chloride that had been left exposed to sunlight. for the hazard and dose-response assessment in IRIS pertaining to chronic exposure to vinyl chloride. Compendium of Chemical Hazards: Vinyl Chloride Page 3 of 4 General Information Exposure to vapours can cause weakness, effects on balance, headache, fatigue, numbness, tingling sensation, nausea, vomiting, stomach pain and sight and hearing disturbances, coughing, wheezing and breathlessness, headache and drowsiness. For more than 30 years, leading health, environmental justice, and health-impacted organizations across the country and world have been campaigning to phase out this poison plastic. VINYL CHLORIDE In Drinking Water Prepared by Pesticide and Environmental Toxicology Section Office of Environmental Health Hazard Assessment California Environmental Protection Agency October 1999 . It is flammable (burns easily) as a gas and is not stable at high temperatures. Direct contact with open flames or a high energy heat source will result in combustion. Spillages and … HEALTH HAZARDS 6.1 Vinyl chloride is a gas, or a liquid when under pressure, at room temperature, so the primary route of exposure is by inhalation (see Appendix 1 for physical and chemical properties of vinyl chloride). EC Number 200-831-0. Vinyl Chloride Monomer (VCM) is a colorless, flammable gas at room temperature. About 13 … Danger that the substance can be violently or explosively reactive. IA; H350 03 - HAZARDS IDENTIFICATION MOST IMPORTANT HAZARDS SAFETY INFORMATION : PLEASE READ THIS SHEET CAREFULLY HEALTH EFFECTS Toxic; May cause cancer; Carcinogenicity, 1A, H350 PHYSICAL AND CHEMICAL HAZARDS Extremely flammable, 1, H220 … Vinyl chloride exists in liquid form if it is kept under high pressure or at low temperatures (less than -13.4�C). The purpose of the national emission standard for hazardous air pollutants (NESHAP) is to minimize vinyl chloride emissions from process and fugitive emission sources in ethylene dichloride, vinyl chloride and polyvinyl chloride production categories to the level attainable with best available control technology. Regulations strictly limit levels of vinyl chloride in the workplace and in emissions from manufacturing plants. Employers shall ensure that each employee has access to labels on containers of vinyl chloride and to safety data sheets, and is trained in accordance with the requirements of HCS and paragraph (j) of this section. Category 1 . PubChem Substance ID 24864136 Known human Carcinogen . Vinyl is manufactured by polymerizing (linking together) a chemical called vinyl chloride. Breathing high levels of vinyl chloride for short periods of time can cause dizziness, sleepiness, unconsciousness, and at extremely high levels can cause death. Polyvinyl chloride (PVC) is a widely used building material praised for its durability, yet criticized for its potential health hazards. Vinyl Chloride: Toxic Hazards and Precautions (Environmental Hygiene Guidance Note) | Health and Safety Executive (HSE) | ISBN: 9780118857307 | Kostenloser Versand für alle Bücher mit Versand und Verkauf duch Amazon. Many scientists believe there is no safe level of exposure to a carcinogen. Specific target organ toxicity - Single and repeated exposure . Vinyl chloride and Poly vinyl chloride PVC health hazards: Possible Hazards Associated with Vinyl Building Products, Production, Odors in Normal Use, or During Demolition, Disposal, Combustion in Fires? The harmful health effects of vinyl chloride have been known for decades, though industry has suppressed and misrepresented the health effects from PVC exposures for years. Vinyl chloride | H2C=CHCl or (C2H3Cl)n or C2H3Cl | CID 6338 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. This page contains information on the chemical Vinyl chloride including: 115 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and 3 proper shipping names; USDOT 2008 Emergency Response Guidebook initial response information for 2 related materials. Cancer Hazard Vinyl Chloride is a CARCINOGEN in humans. Skin corrosion/irritation . The vapour forms an explosive mixture with air. Cat. This colorless compound is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC). Compendium of Chemical Hazards: Vinyl Chloride Page 2 of 11 Incident Management Hazard Identification Standard (UK) dangerous goods emergency action codes UN 1086 Vinyl chloride, stabilized EAC 2YE Use fine water spray can be used. From production through disposal, vinyl chloride threatens health and contaminates the environment. may produce symptoms of central nervous system depression including headache, dizziness, nausea, loss of balance and drowsiness. DRAFT DRAFT FOR PUBLIC COMMENT AND iii SCIENTIFIC REVIEW October 1999 … SECTION 2 – HAZARDS IDENTIFICATION . Wear normal fire kit in combination with breathing apparatus*. Polyvinyl chloride was accidentally discovered on at least two different occasions in the 19th century, first in 1835 by Henri Victor Regnault and in 1872 by Eugen Baumann. 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